Table 2.
entry | substrate | product | time (h) | yielda |
---|---|---|---|---|
1 | 3 | 79% | ||
2 | 12 | 7% | ||
3b | 1 | 91% | ||
4 | 4 | 78% | ||
5 | 6 | 82% | ||
6 | 12 | 0% | ||
7 | 12 | 0% | ||
8 | 12 | 0% | ||
9 | 12 | 0% | ||
10 | 2 | >95%c | ||
11 | 2 | 90%c | ||
12 | 1 | >95%c | ||
13 | 2 | 83% |
Footnotes:
Yields refer to isolated, purified products.
2 equivalents of Mn(OAc)3 were used.
Calculated by 1H NMR using 1,3,5-trimethoxybenzene as an internal standard.