Table 1.
Esters | Days | Cheeses | |||||
---|---|---|---|---|---|---|---|
A1 | A2 | B1 | B2 | C1 | C2 | ||
Formic acid ethyl ester | 2 | 0.28 ± 0.09 abB | 0.20 ± 0.04bA | 0.41 ± 0.03aC | 0.17 ± 0.04bB | 0.30 ± 0.01abB | 0.17 ± 0.04bB |
90 | 0.65 ± 0.01aA | 0.39 ± 0.11bcA | 0.63 ± 0.01aB | 0.34 ± 0.03cA | 0.61 ± 0.09abAB | 0.31 ± 0.02cAB | |
180 | 0.86 ± 0.09aA | 0.51 ± 0.14abcA | 0.85 ± 0.03aA | 0.40 ± 0.03bcA | 0.76 ± 0.16abA | 0.36 ± 0.05cA | |
Ethyl acetate | 2 | 0.09 ± 0.03aA | 0.03 ± 0.00aB | 0.09 ± 0.03aA | 0.04 ± 0.01aA | 0.09 ± 0.00aB | 0.03 ± 0.01aA |
90 | 0.18 ± 0.04aA | 0.06 ± 0.01bA | 0.13 ± 0.02abA | 0.06 ± 0.01bA | 0.17 ± 0.02aAB | 0.05 ± 0.01bA | |
180 | 0.22 ± 0.09aA | 0.07 ± 0.00aA | 0.19 ± 0.04aA | 0.08 ± 0.03aA | 0.21 ± 0.03aA | 0.07 ± 0.01aA | |
Ethylbutanoate | 2 | 0.36 ± 0.13aB | 0.15 ± 0.01aB | 0.35 ± 0.04aC | 0.18 ± 0.02aB | 0.30 ± 0.01aC | 0.17 ± 0.03aB |
90 | 0.93 ± 0.07aAB | 0.35 ± 0.09bAB | 0.79 ± 0.10aB | 0.39 ± 0.03bA | 0.78 ± 0.15aB | 0.38 ± 0.02bA | |
180 | 1.23 ± 0.19aA | 0.50 ± 0.07bA | 1.09 ± 0.06aA | 0.47 ± 0.05bA | 1.01 ± 0.05aA | 0.47 ± 0.02bA | |
Propylbutanoate | 2 | 0.26 ± 0.01aB | 0.09 ± 0.00aB | 0.19 ± 0.04aA | 0.09 ± 0.01aB | 0.23 ± 0.11aA | 0.11 ± 0.01aA |
90 | 0.60 ± 0.16aAB | 0.26 ± 0.04aA | 0.46 ± 0.15aA | 0.20 ± 0.03aA | 0.49 ± 0.16aA | 0.19 ± 0.04aA | |
180 | 0.72 ± 0.06aA | 0.33 ± 0.00abA | 0.58 ± 0.23abA | 0.24 ± 0.03bA | 0.67 ± 0.15abA | 0.24 ± 0.05bA | |
Isoamylacetate | 2 | 0.22 ± 0.02abB | 0.09 ± 0.02bcB | 0.23 ± 0.03aA | 0.12 ± 0.04abcA | 0.23 ± 0.02aA | 0.08 ± 0.05cA |
90 | 0.46 ± 0.07aA | 0.09 ± 0.04bB | 0.13 ± 0.08bA | 0.05 ± 0.03bA | 0.15 ± 0.09bA | 0.06 ± 0.03bA | |
180 | 0.36 ± 0.06abAB | 0.25 ± 0.02aA | 0.28 ± 0.01aA | 0.23 ± 0.10aA | 0.35 ± 0.05aA | 0.22 ± 0.04aA | |
Hexanoic acid ethyl ester | 2 | 0.44 ± 0.01abB | 0.24 ± 0.01bB | 0.53 ± 0.14abC | 0.30 ± 0.11abA | 0.64 ± 0.13aB | 0.32 ± 0.11abA |
90 | 2.54 ± 0.15aA | 0.58 ± 0.10cAB | 1.67 ± 0.03bB | 0.46 ± 0.07cA | 2.02 ± 0.18bA | 0.54 ± 0.17cA | |
180 | 2.19 ± 0.19aA | 0.79 ± 0.11bA | 2.39 ± 0.14aA | 0.61 ± 0.10bA | 2.18 ± 0.32aA | 0.60 ± 0.11bA | |
Ethyl octanoate | 2 | 0.20 ± 0.06bcA | 0.13 ± 0.02cB | 0.30 ± 0.02abA | 0.06 ± 0.04c | 0.36 ± 0.03aA | 0.07 ± 0.04cA |
90 | 0.35 ± 0.13aA | 0.19 ± 0.03aAB | 0.16 ± 0.11aA | 0.08 ± 0.03a | 0.22 ± 0.11aA | 0.19 ± 0.00aA | |
180 | 0.42 ± 0.04aA | 0.25 ± 0.00aA | 0.35 ± 0.11aA | 0.22 ± 0.08a | 0.39 ± 0.12aA | 0.23 ± 0.07aA | |
Butanoic acid hexyl ester | 2 | 0.78 ± 0.00aA | 0.39 ± 0.06bA | 0.67 ± 0.00aA | 0.36 ± 0.02bA | 0.68 ± 0.00aA | 0.30 ± 0.06bA |
90 | 1.16 ± 0.26aA | 0.47 ± 0.02bA | 0.91 ± 0.15abA | 0.41 ± 0.01bA | 1.05 ± 0.16aA | 0.41 ± 0.06bA | |
180 | 1.15 ± 0.31aA | 0.47 ± 0.11aA | 1.10 ± 0.32aA | 0.47 ± 0.06aA | 1.11 ± 0.17aA | 0.47 ± 0.04aA |
Data are expressed as relative peak chromatographic area. Mean values followed by different lowercase letters within a row indicate significant differences between cheese samples (p < 0.05)
Mean values followed by different uppercase letters within a column for same compound indicate significant differences between ripening periods (p < 0.05)
(A): 100 % ewe milk, (B): 50 % ewe milk + % 50 cow milk, (C): 50 % ewe milk + 25 % cow milk + 25 % goat milk