Table 2.
Acids | Days | Cheeses | |||||
---|---|---|---|---|---|---|---|
A1 | A2 | B1 | B2 | C1 | C2 | ||
Acetic acid | 2 | 7.31 ± 0.36aB | 2.17 ± 0.06bB | 7.54 ± 0.28aA | 1.53 ± 0.23bB | 7.00 ± 0.64aA | 1.53 ± 0.23bA |
90 | 11.86 ± 3.29aAB | 3.68 ± 0.17bA | 7.80 ± 2.45abA | 3.51 ± 0.02bA | 10.37 ± 2.06abA | 3.11 ± 0.86bA | |
180 | 21.89 ± 4.02aA | 3.96 ± 0.57cA | 12.97 ± 0.49bA | 3.06 ± 0.37cA | 12.15 ± 1.53bA | 3.26 ± 0.44cA | |
Propionic acid | 2 | 0.30 ± 0.12aB | 0.22 ± 0.06aA | 0.21 ± 0.09Aa | 0.12 ± 0.02aB | 0.20 ± 0.07aB | 0.08 ± 0.04aB |
90 | 0.73 ± 0.19aAB | 0.29 ± 0.04aA | 0.53 ± 0.20aA | 0.23 ± 0.03aAB | 0.54 ± 0.18aA | 0.22 ± 0.01aA | |
180 | 1.09 ± 0.10aA | 0.57 ± 0.21abA | 0.79 ± 0.21abA | 0.34 ± 0.04bA | 0.65 ± 0.13abA | 0.25 ± 0.00bA | |
Butanoic acid | 2 | 2.30 ± 0.26aB | 0.78 ± 0.11bB | 2.40 ± 0.24aB | 0.74 ± 0.26bA | 2.20 ± 0.07aB | 0.74 ± 0.15bA |
90 | 4.37 ± 0.07aB | 1.47 ± 0.27bB | 3.44 ± 0.68aB | 1.52 ± 0.33bA | 3.73 ± 0.73aB | 1.11 ± 0.43bA | |
180 | 10.64 ± 2.30aA | 2.80 ± 0.22bA | 7.93 ± 0.06aA | 2.44 ± 0.99bA | 7.71 ± 0.58aA | 1.85 ± 0.69bA | |
Hexanoic acid | 2 | 5.10 ± 0.20aB | 1.60 ± 0.13cB | 3.95 ± 0.08bB | 1.46 ± 0.07cC | 4.26 ± 0.46abB | 1.33 ± 0.11cB |
90 | 7.07 ± 0.17aB | 2.49 ± 0.12bAB | 5.26 ± 1.04aB | 2.67 ± 0.01bB | 5.39 ± 0.57aB | 1.86 ± 0.11bB | |
180 | 16.54 ± 1.76aA | 3.59 ± 0.58bA | 15.13 ± 1.27aA | 3.93 ± 0.25bA | 14.92 ± 2.82aA | 2.86 ± 0.19bA | |
Octanoic acid | 2 | 1.53 ± 0.20aC | 0.51 ± 0.05bB | 1.38 ± 0.04aC | 0.49 ± 0.07bB | 1.28 ± 0.11aC | 0.50 ± 0.06bB |
90 | 5.94 ± 0.07aB | 2.92 ± 0.03cdA | 4.10 ± 0.64bcB | 2.15 ± 0.14dA | 4.30 ± 0.37bB | 1.95 ± 0.38dA | |
180 | 14.10 ± 1.51aA | 3.04 ± 0.42cA | 6.81 ± 0.70bA | 2.38 ± 0.21cA | 8.28 ± 0.60bA | 2.20 ± 0.28cA | |
Nonanoic acid | 2 | 0.06 ± 0.00aA | 0.03 ± 0.00aA | 0.05 ± 0.03aA | 0.03 ± 0.00aA | 0.06 ± 0.02aA | 0.03 ± 0.01aA |
90 | 0.15 ± 0.05aA | 0.05 ± 0.00aA | 0.08 ± 0.03aA | 0.05 ± 0.01aA | 0.09 ± 0.03aA | 0.05 ± 0.02aA | |
180 | 0.13 ± 0.02A | 0.06 ± 0.01bA | 0.12 ± 0.00aA | 0.06 ± 0.00bA | 0.13 ± 0.00aA | 0.06 ± 0.01bA | |
Decanoic acid | 2 | 0.35 ± 0.08aB | 0.12 ± 0.01bC | 0.33 ± 0.07abB | 0.15 ± 0.02abC | 0.36 ± 0.08aB | 0.14 ± 0.01abC |
90 | 5.95 ± 0.21aA | 2.81 ± 0.08bcA | 4.01 ± 1.14abA | 2.05 ± 0.05bcA | 3.54 ± 0.57bAB | 1.42 ± 0.10cB | |
180 | 4.85 ± 1.02aA | 1.48 ± 0.35bB | 3.53 ± 0.78abAB | 1.69 ± 0.04bB | 4.32 ± 0.18aA | 1.78 ± 0.07bA | |
Benzoic acid | 2 | 0 ± 0A | 0 ± 0A | 0 ± 0A | 0 ± 0A | 0 ± 0A | 0 ± 0B |
90 | 0.03 ± 0.05aA | 0.02 ± 0.02aA | 0.03 ± 0.05aA | 0.03 ± 0.02aA | 0.04 ± 0.03aA | 0.03 ± 0.01aAB | |
180 | 0.04 ± 0.05aA | 0.03 ± 0.04aA | 0.04 ± 0.05aA | 0.03 ± 0.01aA | 0.06 ± 0.03aA | 0.04 ± 0.01aA | |
Dodecanoic acid | 2 | 0 ± 0C | 0 ± 0C | 0 ± 0C | 0 ± 0B | 0 ± 0B | 0 ± 0C |
90 | 0.44 ± 0.10aB | 0.09 ± 0.02cB | 0.33 ± 0.06abB | 0.09 ± 0.02cAB | 0.45 ± 0.03aAB | 0.16 ± 0.03bcB | |
180 | 0.71 ± 0.05abA | 0.25 ± 0.01bA | 0.73 ± 0.11abA | 0.28 ± 0.10abA | 0.87 ± 0.34aA | 0.34 ± 0.01abA |
Data are expressed as relative peak chromatographic area. Mean values followed by different lowercase letters within a row indicate significant differences between cheese samples (p < 0.05)
Mean values followed by different uppercase letters within a column for same compound indicate significant differences between ripening periods (p < 0.05)
(A): 100 % ewe milk, (B): 50 % ewe milk + % 50 cow milk, (C): 50 % ewe milk + 25 % cow milk + 25 % goat milk