Fig. 4.

a Square wave voltammograms (frequency: 100 Hz, amplitude: 40 mV, step potential: 1 mV) for the oxidation of THC, seen at ca. +0.37 V (vs. SCE), on the graphite/mineral oil paste electrode. The measurement was obtained in a deoxygenated BBS (0.1 M KCl, pH=10.0, 298 K), after immersing the electrode in stationary deoxygenated synthetic saliva/BBS solutions that contained 0.10 – 16 μM THC, for 5 minutes. b The increase of the peak current with increasing THC concentration (black squares) with the correlation line through the linear range (red line, R² = 0.99). The lower practical limit of detection was determined as being 0.50 μM, while the slope of the calibration curve gave a value of 0.067 μA μM⁻¹ for the sensitivity of the sensor. The errors relate to separate electrode preparations