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Catalyst screen in the presence of E. coli.
| Entry | Catalyst (mol%) | Yield (%) 75 | trans:cis |
|---|---|---|---|
| 1 | FeTPPCl (10) | 3.9:1 | |
| 2 | Fe(F20TPP)Cl (10) | 55 | 5.1:1 |
| 3 | Fe(OMe)4TPPCl (10) | 7 | 2.9:1 |
| 4 | hemin (10) | 0 | – |
| 5 | FePcCl (10) | 95 | 3.4:1 |
| 6 | FePcCl (5) | 93[a] | 3.4:1 |
| 7 | FePcCl (2.5) | 90[b] | 3.7:1 |
| 8 | FePcCl (1) | 80[b] | 4.0:1 |
Reactions were performed as described in Table 1. All data is shown as an average of three experiments.
24 h reaction.
48 h reaction.
