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. 2015 Apr 23;54(23):6870–6873. doi: 10.1002/anie.201500596

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© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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Scheme 3 — Olefin isomerization followed by intramolecular hydroacylation. a) [Rh((±)-L1)]BF₄ (10 mol %), acetone, 60 °C, 17 h. The 16/17 ratios were obtained for the reaction performed at room temperature.