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EXAFS Fitting Results for [MnIIIMnIV(μ-O)2(N4py)2]3+ Complex.
| Mn–O
|
Mn––N
|
Mn···C
|
Mn···Mn
|
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| n | r (Å) | σ2 × 103 (Å)2 | n | r (Å) | σ2 × 103 (Å)2 | n | r (Å) | σ2 × 103 (Å)2 | n | r (Å) | σ2 × 103 (Å)2 | |
| [MnIIIMnIV(μ-O)2(N4py)2]3+ | 2 | 1.79 | 4.2 | 2 | 2.00 | 3.6 | 4 | 2.81 | 4.4 | 1 | 2.63 | 1.8 |
| 1 | 2.17 | 3.7 | 5 | 2.96 | 4.2 | |||||||
Fourier transform range for [MnIIIMnIV(μ-O)2(N4py)2]3+: k = 2 – 14.3 Å−1 (resolution 0.128 Å).
