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. 2014 Feb 24;53(14):3731–3734. doi: 10.1002/anie.201400027

Scheme 3.

Scheme 3

Deracemization of benzylisoquinolines rac-1 to berbines (S)-2 by a MAO/BBE/borane redox cascade (performed either in a stepwise or a concurrent fashion). MAO=monoamine oxidase MAO-N (variant D11).