Table 1. Biogenic benzenoid volatile compounds.
Compound | Biogenic driver |
Biogenic (MEGAN v2.1) |
Biogenic (possible range) | Anthropogenic (EDGAR) | Biogenic SOA (mostly low NOx) | Anthropogenic SOA (mostly high NOx) | |
---|---|---|---|---|---|---|---|
Emission factor | Global emission | Global emission | Global emission | Potential global source range | Potential global source | ||
μg m2 h−1 | Tg y−1 | Tg y−1 | Tg y−1 | Tg y−1 | Tg y−1 | ||
toluene | multiple | 9 | 1.5 | 1 to 6b | 7.6 | 0.3 to 3.0 | 0.6 to 4.5 |
benzene | multiple | 0 | 0 | 0.1 to 1 | 6.1 | 0.04 to 0.4 | 0.5 to 3.3 |
xylene | multiple | 0 | 0 | 0.1 to 0.5 | 5.2 | 0.04 to 0.2 | 0.4 to 2.2 |
othera | 37 | 6.6 | 3 to 33 | 5.5 | 1.0 to 11 | 0.2 to 1.8 | |
Total | 46 | 8.1 | 4 to 40 | 24.4 | 1.4 to 15 | 2.0 to 12 | |
aother biogenic benzenoids | |||||||
homosalate | sunscreen | 8.4 | 2.0 | 1 to 10 | |||
ethylhexenyl salate | sunscreen | 4.2 | 0.98 | 0.5 to 5 | |||
cymene <para-> | foliar, floral | 7.5 | 0.9 | 0.5 to 5 | |||
cymene <ortho-> | foliar, floral | 4.5 | 0.54 | 0.2 to 3 | |||
methyl salicylate | stress | 9 | 1.5 | 0.3 to 3 | |||
p-cymenene (dimethyl styrene) | unknown | 0.3 to 0.6 | 0.05 | <0.1 to 1 | |||
estragole (methyl chavicol) | floral, fruit conifer | 0.9 to 1.65 | 0.18 | 0.1 to 5 | |||
indole | stress | 0.6 | 0.1 | <0.1 to 0.2 | |||
benzaldehyde | stress | 0.15 | 0.05 | <0.1 to 0.2 | |||
methyl benzoate | unknown | 0.15 | 0.05 | <0.1 to 0.1 | |||
m-cymenene | unknown | 0.3 | 0.04 | <0.1 to 0.1 | |||
phenylacetaldehyde | unknown | 0.15 | 0.05 | <0.1 to 0.1 | |||
anisole | floral | 0.15 | 0.05 | <0.1 to 0.1 | |||
benzyl acetate | floral | 0.3 | 0.1 | <0.1 to 0.2 | |||
benzyl alcohol | floral | 0.15 | 0.05 | <0.1 to 0.1 | |||
eugenol | stress | 0 | <0.02 | <0.1 to 0.2 | |||
cinnamic acid | stress, floral | 0 | <0.02 | <0.1 to 0.1 | |||
coniferyl alcohol | unknown | 0 | <0.02 | <0.1 to 0.1 | |||
chavicol | floral | 0 | <0.02 | <0.1 to 0.1 | |||
safrole | unknown | 0 | <0.02 | <0.1 to 0.1 | |||
ethyl cinnamate | unknown | 0 | <0.02 | <0.1 to 0.1 | |||
salicylic aldehyde | stress | 0 | <0.02 | <0.1 to 0.2 |
Compared are emission factors and global emission estimates used by MEGAN, and possible global ranges based on current understanding. In addition, comparison with anthropogenic benzenoid compounds is given.
aother biogenic benzenoids,
bincludes emissions from picoplankton and E. hux of 1.6 Tg y−1.