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. 2015 Jul 13;5:12064. doi: 10.1038/srep12064

Table 1. Biogenic benzenoid volatile compounds.

Compound Biogenic driver Biogenic (MEGAN v2.1)
Biogenic (possible range) Anthropogenic (EDGAR) Biogenic SOA (mostly low NOx) Anthropogenic SOA (mostly high NOx)
Emission factor Global emission Global emission Global emission Potential global source range Potential global source
μg m2 h−1 Tg y−1 Tg y−1 Tg y−1 Tg y−1 Tg y−1
toluene multiple 9 1.5 1 to 6b 7.6 0.3 to 3.0 0.6 to 4.5
benzene multiple 0 0 0.1 to 1 6.1 0.04 to 0.4 0.5 to 3.3
xylene multiple 0 0 0.1 to 0.5 5.2 0.04 to 0.2 0.4 to 2.2
othera   37 6.6 3 to 33 5.5 1.0 to 11 0.2 to 1.8
Total   46 8.1 4 to 40 24.4 1.4 to 15 2.0 to 12
aother biogenic benzenoids
homosalate sunscreen 8.4 2.0 1 to 10      
ethylhexenyl salate sunscreen 4.2 0.98 0.5 to 5      
cymene <para-> foliar, floral 7.5 0.9 0.5 to 5      
cymene <ortho-> foliar, floral 4.5 0.54 0.2 to 3      
methyl salicylate stress 9 1.5 0.3 to 3      
p-cymenene (dimethyl styrene) unknown 0.3 to 0.6 0.05 <0.1 to 1      
estragole (methyl chavicol) floral, fruit conifer 0.9 to 1.65 0.18 0.1 to 5      
indole stress 0.6 0.1 <0.1 to 0.2      
benzaldehyde stress 0.15 0.05 <0.1 to 0.2      
methyl benzoate unknown 0.15 0.05 <0.1 to 0.1      
m-cymenene unknown 0.3 0.04 <0.1 to 0.1      
phenylacetaldehyde unknown 0.15 0.05 <0.1 to 0.1      
anisole floral 0.15 0.05 <0.1 to 0.1      
benzyl acetate floral 0.3 0.1 <0.1 to 0.2      
benzyl alcohol floral 0.15 0.05 <0.1 to 0.1      
eugenol stress 0 <0.02 <0.1 to 0.2      
cinnamic acid stress, floral 0 <0.02 <0.1 to 0.1      
coniferyl alcohol unknown 0 <0.02 <0.1 to 0.1      
chavicol floral 0 <0.02 <0.1 to 0.1      
safrole unknown 0 <0.02 <0.1 to 0.1      
ethyl cinnamate unknown 0 <0.02 <0.1 to 0.1      
salicylic aldehyde stress 0 <0.02 <0.1 to 0.2      

Compared are emission factors and global emission estimates used by MEGAN, and possible global ranges based on current understanding. In addition, comparison with anthropogenic benzenoid compounds is given.

aother biogenic benzenoids,

bincludes emissions from picoplankton and E. hux of 1.6 Tg y−1.