Table 1. Polarization Enhancement (ε) Values for Three Aromatic Proton Sites of Pyridine (Figures 4, 5, and 7) Achieved via Conventional (ex Situ, Low-Field) SABRE and Detected by High-Resolution 1H NMR Spectroscopy Using the Nanoscale Catalysts (PVPCs or NPCs) in d6-Ethanol or d4-Methanola.
catalyst | ε(Ho) | ε(Hp) | ε(Hm) |
---|---|---|---|
PVPCs (30 s) | –7 | –6 | –3 |
NPCs (30 s) | –18 | –17 | –7 |
NPCs (300 s) | –26 | –39 | –11 |
NPCs recycled | –11 | –9.7 | –3.2 |
Reported ε values are calculated from spectral integrals and are approximate, with estimated uncertainties of ∼10%. Numbers in parentheses are pH2 bubbling times.