Skip to main content
. 2015 Mar 11;119(13):7525–7533. doi: 10.1021/acs.jpcc.5b02036

Table 1. Polarization Enhancement (ε) Values for Three Aromatic Proton Sites of Pyridine (Figures 4, 5, and 7) Achieved via Conventional (ex Situ, Low-Field) SABRE and Detected by High-Resolution 1H NMR Spectroscopy Using the Nanoscale Catalysts (PVPCs or NPCs) in d6-Ethanol or d4-Methanola.

catalyst ε(Ho) ε(Hp) ε(Hm)
PVPCs (30 s) –7 –6 –3
NPCs (30 s) –18 –17 –7
NPCs (300 s) –26 –39 –11
NPCs recycled –11 –9.7 –3.2
a

Reported ε values are calculated from spectral integrals and are approximate, with estimated uncertainties of ∼10%. Numbers in parentheses are pH2 bubbling times.