Table 2.
Description of catalysts prepared for ammonia synthesis.
Precursor | Support | Ru wt % after thermal activation |
Ru5C(CO)15 (2) | CNF–PPh2 | 2.3 |
Ru5PtC(CO)14(COD) (4) | CNF–PPh2 | 3.0 |
Ru5C(CO)14(Au{PPh3})2 (6) | CNF–PPh2 | 2.6 |
Ru5PtC(CO)15(Au{PPh3})2 (8) | CNF–PPh2 | 2.3 |
PPN[Ru3Co(CO)13] (9) | CNF–NMe3+ | 1.7 |