Skip to main content
. 2015 Jul 3;11:1112–1122. doi: 10.3762/bjoc.11.125

Table 3.

Copper-mediated N-arylation of MPTTFs.

MPTTF Ar-X Product Conditions % Yield
Inline graphic
4c′ 		23-Br Inline graphic
4m 		STa 35
MWb 81
Inline graphic
4d′ 		23-Br Inline graphic
4n 		ST 68
MW 93
Inline graphic
4f′ 		24-I Inline graphic
4o 		Refluxc 67
MW 54
Inline graphic
4c′ 		25-I Inline graphic
4p 		ST 35
Inline graphic
4c′ 		26-I Inline graphic
4q 		ST 52
Inline graphic
4d′ 		26-I Inline graphic
4r 		ST 65
Inline graphic
4g′ 		23-Br Inline graphic
4s 		ST 25
Inline graphic
4d′ 		25-I Inline graphic
4t 		MW 82 [56]
Inline graphic
4d′ 		26-I Inline graphic
4u 		MW 51
Inline graphic
4d′ 		27-I Inline graphic
4v 		MW 80
Inline graphic
4d′ 		28-I Inline graphic
4w 		MW 64

aST = sealed tube conditions; bMW = microwave conditions; cReflux = conventional reflux.