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. 2015 Jul 13;11:1155–1162. doi: 10.3762/bjoc.11.130

Scheme 1.

Scheme 1

Cinnamates bearing a nitroxyl moiety 5ai from 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl (3) and iodobenzene derivatives; (i) CH2=CH–COCl (2), NEt3, benzene, 90–95%; (ii) R–Ar–I 4ai, PdEnCat TOTP30, Bu4N+AcO, toluene, 80–100 °C, 30–100%.