Table 1. Protonation and complex formation constants for DFO, DFP and DFX with iron(III), copper(II) and zinc(II) from literature.
DFO | DFP | DFX | ||||||
---|---|---|---|---|---|---|---|---|
Species | log β | pK | Species | log β | pK | Species | log β | pK |
[LH]2- | [20]10.84 | 10.84 | [LH]0 | [14]9.82 | 9.82 | [LH]2- | [21]10.61 | 10.61 |
[LH2]- | 20.3 | 9.4 | [LH2]+ | 13.48 | 3.66 | [LH2]- | 19.61 | 9.00 |
[LH3]0 | 29.3 | 9.0 | [LH3]0 | 23.32 | 3.71 | |||
[LH4]+ | 37.6 | 8.3 | ||||||
[FeLH]+ | [22]41.01 | 10.61 | [FeLH]+ | [21, 23]24.3 | 2.3 | |||
[FeL]0 | 30.4 | [FeL]2+ | [14]15.01 | [FeL]0 | 22.0 | |||
[FeL2H2]- | 43.4 | 2.2 | ||||||
[FeL2H]2- | 41.2 | 4.3 | ||||||
[FeL2]+ | 27.30 | [FeL2]3- | 36.9 | |||||
[FeL3]0 | 37.43 | |||||||
[ZnLH3]2+ | [20]33.4 | 5.2 | ||||||
[ZnLH2]+ | 28.17 | 7.77 | ||||||
[ZnLH]0 | 20.4 | 10.1 | ||||||
[ZnL]- | 10.32 | [ZnL]+ | [24] 7.24 | [ZnL]- | [21, 23]12.1 | |||
[ZnL2]-4 | 16 | |||||||
[ZnL2]0 | 13.55 | 11.25 | ||||||
[ZnL2H-1]-1 | 2.30 | |||||||
[ZnL3]-1 | 15.2 | |||||||
[CuLH3]2+ | [20]36.99 | 3.89 | ||||||
[CuLH2]+ | 33.1 | 9.1 | ||||||
[CuLH]0 | 23.98 | 10.24 | ||||||
[CuL]- | 13.74 | [CuL]+ | [14]10.42 | [CuL]- | [21, 23]17.6 | |||
[CuL2]-4 | 22.4 | |||||||
[CuL2H]+ | 21.98 | 2.89 | ||||||
[CuL2]0 | 19.09 | 10.60 | ||||||
[CuL2H-1]-1 | 8.49 | |||||||
[Cu2LH]2+ | 32.09 |