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. 2015 Jul 20;10(7):e0133050. doi: 10.1371/journal.pone.0133050

Table 1. Protonation and complex formation constants for DFO, DFP and DFX with iron(III), copper(II) and zinc(II) from literature.

DFO DFP DFX
Species log β pK Species log β pK Species log β pK
[LH]2- [20]10.84 10.84 [LH]0 [14]9.82 9.82 [LH]2- [21]10.61 10.61
[LH2]- 20.3 9.4 [LH2]+ 13.48 3.66 [LH2]- 19.61 9.00
[LH3]0 29.3 9.0 [LH3]0 23.32 3.71
[LH4]+ 37.6 8.3
[FeLH]+ [22]41.01 10.61 [FeLH]+ [21, 23]24.3 2.3
[FeL]0 30.4 [FeL]2+ [14]15.01 [FeL]0 22.0
[FeL2H2]- 43.4 2.2
[FeL2H]2- 41.2 4.3
[FeL2]+ 27.30 [FeL2]3- 36.9
[FeL3]0 37.43
[ZnLH3]2+ [20]33.4 5.2
[ZnLH2]+ 28.17 7.77
[ZnLH]0 20.4 10.1
[ZnL]- 10.32 [ZnL]+ [24] 7.24 [ZnL]- [21, 23]12.1
[ZnL2]-4 16
[ZnL2]0 13.55 11.25
[ZnL2H-1]-1 2.30
[ZnL3]-1 15.2
[CuLH3]2+ [20]36.99 3.89
[CuLH2]+ 33.1 9.1
[CuLH]0 23.98 10.24
[CuL]- 13.74 [CuL]+ [14]10.42 [CuL]- [21, 23]17.6
[CuL2]-4 22.4
[CuL2H]+ 21.98 2.89
[CuL2]0 19.09 10.60
[CuL2H-1]-1 8.49
[Cu2LH]2+ 32.09