Table 1.
BET specific surface area (SSA), micropore volume (Vm), room-temperature CO2 uptake, and CO2/N2 selectivity of all the nZDCs before and after acid treatment (represented by a and c) and nZIF-8.
| Sample | SSA | Vm | CO2 uptake at 25 °C [mmol g−1] |
S
|
||
|---|---|---|---|---|---|---|
| [m2 g−1] | [cm3 g−1] | 0.15 bar | 1.0 bar | 20.0 bar | ||
| ZIF-8 | 1700 | 0.52 | 0.09 | 0.70 | 7.80 | 11 |
| 600a | 517 | 0.15 | 1.08 | 2.24 | 4.77 | 35 |
| 700a | 494 | 0.17 | 1.01 | 2.43 | 4.40 | 34 |
| 800a | 616 | 0.20 | 1.17 | 2.78 | 5.99 | 30 |
| 900a | 834 | 0.29 | 1.24 | 3.35 | 8.16 | 24 |
| 1000a | 1292 | 0.44 | 1.04 | 3.31 | 10.06 | 18 |
| 600c | 716 | 0.25 | 1.09 | 2.66 | 6.48 | 62 |
| 700c | 950 | 0.35 | 1.40 | 3.51 | 7.82 | 79 |
| 800c | 922 | 0.31 | 1.22 | 3.27 | 7.70 | 29 |
| 900c | 925 | 0.34 | 1.10 | 3.21 | 7.80 | 25 |
| 1000c | 1222 | 0.43 | 0.99 | 3.22 | 10.21 | 22 |
