Table 1.
Selected crystallographic data.
| Complex | [GaCl(L)]⋅MeCN | [GaF(L)]⋅2 H2O |
|---|---|---|
| formula | C19H26ClGaN4O4 | C17H27FGaN3O6 |
| M [g−1 mol−1] | 479.61 | 458.14 |
| T [K] | 100(2) | 100(2) |
| crystal system | monoclinic | monoclinic |
| space group (no.) | P21/n (14) | P21/c (14) |
| a [Å] | 12.018(2) | 19.883(3) |
| b [Å] | 13.032(2) | 7.1449(7) |
| c [Å] | 13.230(2) | 13.8880(15) |
| α [°] | 90 | 90 |
| β [°] | 102.373(2) | 106.465(8) |
| γ [°] | 90 | 90 |
| U [Å3] | 2024.0(6) | 1892.1(4) |
| Z | 4 | 4 |
| μ (MoKα) [mm−1] | 1.526 | 1.505 |
| F(000) | 992 | 952 |
| total reflections | 10 274 | 12 106 |
| unique reflections | 4626 | 4303 |
| Rint | 0.029 | 0.089 |
| R1 [Io>2σ(Io)] | 0.030 | 0.067 |
| R1 (all data) | 0.037 | 0.0907 |
| wR2 [Io>2σ(Io)] | 0.077 | 0.144 |
| wR2 (all data) | 0.080 | 0.155 |