Table 1.

Experimental (TIMS), literature,^{8, 26} and theoretical mobility values of molecular adduct complexes from familiar explosives.

Compound	Ionic Form	m/z	TIMS Experimental		Reported Ko (cm2/V·s)	Theoretical CCS (Å2)
			Ko (cm2/V·s)	CCS (Å2)
TNT	[M−H]−	226.010	1.48	143	1.48	136
RDX+NH4Cl	[M+Cl]−	257.003	1.44	147	1.44*	149
RDX+NH4NO3	[M+NO3]−	284.022	1.36	154	1.35*	152
HMX+NH4Cl	[M+Cl]−	331.015	1.29	161	1.25	162
HMX+HCO2	[M+HCOOH-H]−	341.044	1.28	162	-	161
HMX+NH4C2H3O2	[M+CH3COOH-H]−	355.059	1.23	169	-	169
HMX+NH4NO3	[M+NO3]−	358.034	1.23	167	-	165
PETN	[M*]−	316.013	1.37	152	-	151
PETN+NH4Cl	[M+Cl]−	350.982	1.17	178	1.20	182
PETN+HCO2	[M+HCOOH-H]−	361.011	1.14	182	-	179
PETN+NH4NO3	[M+NO3]−	378.001	1.11	187	1.14	188

Literature values used in the TIMS calibration are denoted with *. A K_o error of less than 0.5% was observed in the TIMS replicate measurements.