. 2015 Apr 27;137(20):6680–6691. doi: 10.1021/jacs.5b03284

Table 1. Measured Anisochronicity (¹³C NMR in CDCl₃, 296 K) and Calculated Helical Excess Induced at the Remote Terminus of Foldamers F by Interaction with HA ([F] = 10 mM; [HA] = 12 mM (1.2 Equiv) unless Indicated Otherwise).

graphic file with name ja-2015-03284k_0012.jpg

Entries shaded in grey indicate the greatest levels of non-covalent conformational induction, and these combinations were used further in later experiments.

Measured using 1.5 equiv HA.

Using a ¹⁹F NMR-based probe.

8 equiv. A^–.

10 equiv. A^–.

4 equiv. A^–.

In the presence of 28 vol % methanol; empty table cell, value not measured.

Table 1. Measured Anisochronicity (13C NMR in CDCl3, 296 K) and Calculated Helical Excess Induced at the Remote Terminus of Foldamers F by Interaction with HA ([F] = 10 mM; [HA] = 12 mM (1.2 Equiv) unless Indicated Otherwise).

Table 1. Measured Anisochronicity (¹³C NMR in CDCl₃, 296 K) and Calculated Helical Excess Induced at the Remote Terminus of Foldamers F by Interaction with HA ([F] = 10 mM; [HA] = 12 mM (1.2 Equiv) unless Indicated Otherwise).