Figure 1.

Simulated voltammetric response of a two-electron transfer as a function of the difference between the formal potentials for the two processes. E_f¹−E_f²: +50 mV (magenta), 0 mV (blue), and −50 mV (red). The black line represents the hypothetical limiting case in which the two electrons are transferred simultaneously. Simulations performed using DigiSim; other simulation parameters: v=100 mV s⁻¹, D=10⁻⁵ cm² s⁻¹, r₀=1 mm.