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Computational calculated parameters for a Type III reaction: intramolecular hetero-Diels–Alder cycloaddition (Scheme 4).
| Solvent | μ [D] (most polar species) | Δμ[a] [D] | Ea [kcal mol−1] | ΔH[b] [kcal mol−1] |
|---|---|---|---|---|
| Dichloroethane ionic liquid ([BMIM][PF6]) | 18.2 ([BMIM][PF6]) | 0.3 to 1.4 | 25.7 to 39.7 | −7.5 to −8.9 |
[a] Δμ=μ TS−μ reactants; [b] ΔH=ΔHproducts−ΔHreactants.
