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. 2015 Feb 1;4(3):308–317. doi: 10.1002/open.201402123

Table 7.

Computational calculated parameters for a Type IV reaction: intramolecular [2π+2π] cycloaddition (Scheme 8).

Solvent μ [D] (most polar species) Δμ[a] [D] Ea [kcal mol−1] ΔH[b] [kcal mol−1]
Toluene ionic liquid ([EMIM][PF6]) 18.2 ([EMIM][PF6]) 0.6 29.7 28.8

[a] Δμ=μ TS−μ reactants; [b] ΔH=ΔHproducts−ΔHreactants.