Table 2. One-Pot Borylation/Cross-Coupling Process.

entry	HetAr-X	Ar-X	yield (%)	rxn temp (°C)
1			95	80
2			84	80
3			88 a	80
4			78; 82 a	65
5			39	65
6			86	65
7			79	65
8			59	65
9			63	80
10			53	80
11			31	65
12			61	65
			42	80
13			28	65

^a7.6 mmol scale, 0.75% Pd-G2-XPhos, 1.5% XPhos, 3 equiv ethylene glycol, 3 equiv KOAc, 1.5 equiv BBA