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. Author manuscript; available in PMC: 2016 Aug 4.
Published in final edited form as: Biochemistry. 2015 Jul 21;54(30):4652–4664. doi: 10.1021/acs.biochem.5b00573

Scheme 3.

Scheme 3

Key Steps in Reactions Mechanisms Invoking Reactive Iron-Superoxide Intermediatesa

a(A)Extradiol dioxygenase,73 (B) Tryptophan 2,3-dioxygenase,76–78 (C) phthaloyl peroxide reaction with unactivated aromatic compound.79