Table 2. Aromatic units, p-coumarates and ferulates from Integration of 1H–13C correlation signals in the HSQC spectra of the GEL sample.
RB867515 (RB) | S.spontaneum (AG) | |||||
---|---|---|---|---|---|---|
IN2 | IN5 | IN9 | IN2 | IN5 | IN9 | |
Lignin aromatic units a | ||||||
H (%) | 64.5 b | 13.1 | 7.6 | 74.8 b | 7.0 | 6.3 |
G (%) | 22.0 | 46.9 | 39.4 | 16.3 | 59.0 | 55.6 |
S (%) | 13.5 | 40.0 | 52.9 | 8.9 | 34.1 | 38.1 |
S/G ratio | 0.6 | 0.9 | 1.3 | 0.5 | 0.6 | 0.7 |
p-Hydroxycinnamates c | ||||||
p-Coumarate (%) | 27.6 | 91.0 | 109.9 | 20.9 | 65.3 | 49.7 |
Ferulate (%) | 47.7 | 71.8 | 65.4 | 33.6 | 33.9 | 22.4 |
Ferulate/p-coumarate ratio | 1.7 | 0.8 | 0.6 | 1.6 | 0.5 | 0.5 |
S/Ferulates ratio | 0.3 | 0.6 | 0.8 | 0.3 | 1.0 | 1.7 |
S/p-Coumarate ratio | 0.5 | 0.4 | 0.5 | 0.4 | 0.5 | 0.8 |
aMolar percentages (H+G+S = 100)
bOverestimated due to the presence of proteins
cMolar content as percentage of lignin content (H+G+S = 100)