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. 2015 Mar 6;48(6):1703–1710. doi: 10.1021/acs.macromol.5b00254

Table 1. Copolymerization of AOMEC and εCL at Different Temperatures Initiated by Benzyl Alcohol/TBD or P2-t-Bu.

temperature [°C] catalyst [M]a:[I]:[Cat.] solvent concn [M]
–40 TBD [200]:[1]:[2.5] DCM 2
30 TBD [200]:[1]:[2.5] DCM 2
100 TBD [200]:[1]:[2.5] none bulk
170 TBD [200]:[1]:[2.5] none bulk
30 P2-t-Bu [400]:[1]:[0.5] DCM 2
a

[M], M = nAOMEC + nεCL, and nAOMEC/nεCL = 1.