. 2015 Mar 6;48(6):1703–1710. doi: 10.1021/acs.macromol.5b00254

Table 2. Apparent Rate Constant (k_p^app) at Different Temperatures for AOMEC and εCL during Copolymerization Initiated by Benzyl Alcohol/TBD or P2-t-Bu.

temperature [°C]	catalyst	[M]^a:[I]:[Cat.]	k_p^app(AOMEC)^b [s^–1]	k_p^app(εCL)^b [s^–1]
–40	TBD	[200]:[1]:[2.5]	25	0.064
30	TBD	[200]:[1]:[2.5]	17.1	0.35
100	TBD	[200]:[1]:[2.5]	630	65.4
170	TBD	[200]:[1]:[2.5]	190	102
30	P2-t-Bu	[400]:[1]:[0.5]	101.9	21.5

[M], M = n_AOMEC + n_εCL, and n_AOMEC/n_εCL = 1.

For determination of k_p^app values see Supporting Information figure S1–S5.

Table 2. Apparent Rate Constant (kpapp) at Different Temperatures for AOMEC and εCL during Copolymerization Initiated by Benzyl Alcohol/TBD or P2-t-Bu.