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Programmable printing and rupturing of capsules: (I) multiplexed arrays of aqueous cores containing biomolecular payloads are printed directly on a solid substrate; (II) PLGA solutions containing AuNRs of varying lengths are dispensed directly on the aqueous cores, forming a solid stimuli-responsive shell; (III) the capsules are selectively ruptured via irradiation with a laser wavelength corresponding to the absorption peak of the nanorods.
