Table 2. Selected Structural Parameters of the Cation in Complex 4 Obtained from Single-Crystal X-ray Diffraction Studies (Bond Lengths in Angstroms and Angles in Degrees).
Pt(1)–C(1) | 2.039(2) | N(1)–Pt(1)–C(1) | 85.31(9) |
Pt(1)–N(1) | 2.039(2) | C(1)–Pt(1)–X(1) | 178.95(9) |
Pt(1)–X(1) | 2.169(3) | C(1)–Pt(1)–X(2) | 94.79(10) |
Pt(1)–X(2) | 2.039(2) | N(1)–Pt(1)–X(1) | 94.14(9) |
P(1)–N(1) | 1.622(2) | N(1)–Pt(1)–X(2) | 179.01(9) |
P(1)–C(2) | 1.773(2) | X(1)–Pt(1)–X(2) | 85.78(10) |
P(1)–C(7) | 1.797(3) | C(19)–N(1)–Pt(1) | 125.82(16) |
P(1)–C(13) | 1.797(3) | C(19)–N(1)–P(1) | 116.21(16) |
N(1)–C(19) | 1.444(3) | C(19)–N(1)–P(1) | 116.21(16) |
C(1)–C(2) | 1.409(3) |