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Photocatalytic CO2 Reduction.
| Entry | Photocatalyst | [MC]Ads [μmol g−1] | TOFCO[a] [h−1] | TONCO[b] | TON
[b]
|
|---|---|---|---|---|---|
| 1 | Ru−Re/Acd–PMO | 64 | 109 | 635 | 10 |
| 2 | Ru−Re/MCM-41(I) | 63 | 36 | 254 | 29 |
| 3 | Ru−Re/MeAcd–PMO | 54 | 81 | 294 | 4 |
| 4 | Ru−Re/MCM-41(II) | 57 | 8 | 84 | 10 |
| 5 | (Ru+Re)/Acd–PMO[c] | 62 | – | 33 | 21 |
[a] After 3 h irradiation. [b] The turnover number was calculated based on the metal complex used. [c] Both [MC]Ads of Ru and Re were 62 μmol g−1.
