Table 1.
Cellulose Nanomaterials | Carbon Nanotubes | Ref | |||
---|---|---|---|---|---|
CNCs | CNFs | SWCNTs | MWCNTs | ||
Physical Properties | |||||
Diameter | 5–70 nm | 5–100 nm | 0.4–2 nm | 2–100 nm | 5,44 |
Length | 100–250 nm | several microns | microns-millimeters | microns-centimeters | |
Size distribution | Polydisperse | Polydisperse | Mono- or Polydisperse depending on preparation | Mono- or Polydisperse depending on preparation | |
Tensile Strength | 2–6 GPa | 2–4 GPa | 13–52 GPa | 11–63 GPa | 98–100 |
Young’s Modulus | 50–143 GPa | 15–150 GPa | 0.32–1.47 TPa | 0.27–0.95 TPa | |
Conductivity | None | σ= 102–108 S/m | 44, 100–101 | ||
Optical Properties | Transparent and Iridescent films | Transparent films | None | 102 | |
Life Cycle Assessment | |||||
Manufacturing (Energy requirement) | 500–2,300 kWht−1 | 278,000–250,200,000 kWht−1 | 5 103 | ||
Source | Wood, cotton, hemp, flax, wheat straw, ramie, sugar beet, potato tuber, tunicin, algae, certain bacteria (Gluconacetobacter xylinus) | Fossil fuels | 5 | ||
Cost | $1/g (dry) | $2/g (dry) | $80–$280/g | $8–$15/g | 41 |
$5/g (slurry) | $3/g (slurry) | ||||
Major Use/Application | Paper, packaging, plastic film, cement, automotive components, food products, drug delivery, biomedical implants, wound dressings | Microelectronics, solar cells | Strength enhancers, coatings/films, biosensors, medical devices, drug delivery | 8, 104 | |
Ecotoxicity | Low toxicity | Low toxicity | Oxidative stress and inflammation; Inhalation and dermal exposure considered largest risk | 43, 105 | |
Some proinflammatory cytokines | Some pulmonary inflammation | ||||
Disposal | Biodegradable by organisms with cellulase enzymes | Persistent, non-degradable | 105–106 |
Calculated from suppliers: University of Maine Process Development Center, Cheap Tubes Inc., Buckyusa, Carbon Solutions Inc., U.S. Research Nanomaterials Inc.