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. Author manuscript; available in PMC: 2016 Jun 8.
Published in final edited form as: Angew Chem Int Ed Engl. 2015 Apr 27;54(24):7134–7138. doi: 10.1002/anie.201501505

Table 2.

Tandem Z-selective homodimerization – dihydroxylation of allyl substituted terminal olefins

graphic file with name nihms711195u2.jpg
Entry R (5) Product 6 Yield (%)
1 OCOnPr(5a) graphic file with name nihms711195t1.jpg 6a 72
2 OAc (5b) graphic file with name nihms711195t2.jpg 6b 59
3 OBz (5c) graphic file with name nihms711195t3.jpg 6c 71
4[a] OCO2Ph (5d) graphic file with name nihms711195t4.jpg 6d 61
5 OCONHR (5e) graphic file with name nihms711195t5.jpg 6e 63
6 OCONHR (5f) graphic file with name nihms711195t6.jpg 6f 39
7 NHTs (5g) graphic file with name nihms711195t7.jpg 6g 70
8 NHCBz (5h) graphic file with name nihms711195t8.jpg 6h 53
[a]

Using 1 mol% catalyst in an open vial in the glove box