Table 5. Outcome of co-crystal synthesis.
In this table (
) indicates a co-crystal and () indicates no reaction.
| Donors | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| IF4-COOH | BrF4-COOH | I-COOH | Br-COOH | IF4-OX | BrF4-OX | I- OX | Br- OX | IF4-OH | BrF4-OH | |||
| XB potential (kJmol1) | 167 | 139 | 113 | 87 | 159 | 128 | 101 | 77 | 150 | 126 | ||
| HB potential (kJmol1) | 302 | 288 | 267 | 274 | 247 | 279 | 256 | 259 | 305 | 315 | % Success | |
| Acceptors | 1 |
|
|
|
|
|
|
|
70 | |||
| 2 |
|
|
|
|
|
|
|
|
|
90 | ||
| 3 |
|
|
|
|
|
50 | ||||||
| 4 |
|
|
|
30 | ||||||||
| 5 |
|
|
|
|
|
50 | ||||||
| 6 |
|
|
20 | |||||||||
| 7 |
|
|
|
30 | ||||||||
| 8 |
|
|
|
|
|
50 | ||||||
| 9 |
|
|
|
|
|
|
|
|
|
90 | ||
| 10 |
|
|
|
30 | ||||||||
| 11 |
|
|
|
|
|
|
60 | |||||
| 12 |
|
|
|
|
|
|
60 | |||||
| 13 |
|
|
|
|
|
50 | ||||||
| 14 |
|
|
|
|
|
|
|
70 | ||||
| 15 |
|
|
|
|
|
|
60 | |||||
| 16 |
|
|
|
|
|
|
60 | |||||
| 17 |
|
|
|
|
|
50 | ||||||
| 18 |
|
|
|
|
|
50 | ||||||
| 19 |
|
|
20 | |||||||||
| 20 |
|
|
|
|
|
50 | ||||||
| 12/20 | 8/20 | 9/20 | 8/20 | 14/20 | 11/20 | 8/20 | 6/20 | 14/20 | 14/20 | |||
| % Success | 60 | 40 | 45 | 40 | 70 | 55 | 40 | 30 | 70 | 70 | ||