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. Author manuscript; available in PMC: 2016 Sep 15.
Published in final edited form as: Acta Biomater. 2015 Jun 10;24:53–63. doi: 10.1016/j.actbio.2015.06.004

Figure 1.

Figure 1

(A) Synthetic scheme for ACCL and (B) x%PCL-y%ACPCL SMP networks. (C) 1HNMR of ACCL (400 MHz, CDCl3, 25 °C, TMS): δ = 5.92 (m, 1H;, -CH=CH2 (Gi)), 5.31 (m, 2H; -CH=CH2 (Hii)), 4.63 (m, 2H; -CH=CCH2O (Fii)), 4.20 (m, 2H; -OCH2 (eii)), 3.73 (d, 3J(H,H) = 10.7 Hz, 1H; -CHCH2CH2 (Ai)), 2.40 – 1.50 (m, 6H; -CH2 (bii,cii,dii)). (D) 1H-NMR of 96%PCL-04%ACPCL (400 MHz, CDCl3, 25 °C, TMS): δ = 5.92 (m, 1H;, -CH=CH2 (Gi)), 5.31 (m, 2H; -CH=CH2 (Hii)), 4.63 (m, 2H; -CH=CH2O (Fii)), 4.15 (m, 2H; -OCH2 (eii)), 3.35 (m, 1H; -CHCH2 (Ai)), 2.33 (t, 3J(H,H) = 7.5 Hz, 2H; -CH2 (aii)), 1.96 (m, 2H; -CH2 (Bii)), 1.62 (m, 4H; -CH2 (bii,dii)), 1.39 ppm (m, 2H; -CH2 (cii)). (E) Influence of ACCL:CL feed ratio on x%PCL-y%ACPCL molar composition