Table 3.
Recoveries of OPA vapor spikes from S10 LpDNPH samplers after storage at room temperaturea
| Quantity of OPA vapor collected (µg) |
Period of storage (days) |
Quantity of OPA found (µg) |
Recovery |
|---|---|---|---|
| 0.71 | 3 | 0.68 | 95.8% |
| 0.71 | 6 | 0.66 | 93.0% |
| 0.71 | 10 | 0.61 | 85.9% |
| 0.71 | 15 | 0.69 | 96.8% |
| 5.17 | 3 | 5.15 | 99.6% |
| 5.17 | 6 | 4.99 | 97.1% |
| 5.17 | 10 | 5.24 | 101.3% |
| 5.17 | 15 | 4.85 | 93.8% |
| 14.5 | 3 | 14.4 | 99.3% |
| 14.5 | 6 | 13.5 | 93.1% |
| 14.5 | 10 | 12.2 | 84.1% |
| 14.5 | 15 | 10.9 | 75.2% |
Aliquots of acetonitrile solutions of OPA were deposited on PTFE-GFFs, and pumps operated at 1.0 L min−1 in a nitrogen atmosphere.