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. 2015 Feb 20;17(5):1256–1259. doi: 10.1021/acs.orglett.5b00241

Scheme 5. Scope of Perfluorobenzoates.

Scheme 5

Conditions: Ni(COD)2 (0.1 equiv), PtBu3HBF4 (0.2 equiv), diglyme, 140 °C. Isolated yields are given with GC yields in parentheses (calibrated against hexadecane as the internal standard).

General conditions but with DPPF as ligand (0.125 equiv).

General conditions but with CM-Phos as ligand at 160 °C.

General conditions but at 160 °C.