Table 1. ZFS Parameters and Relative Zero-Field Sublevel Populations for P1 and Linear Oligomers P2–P6 Determined through Simulation of the Transient EPR Spectra Shown in Figure 2.
|D| [MHz] | |E| [MHz] | pX:pY:pZa | |
---|---|---|---|
P1 | 898 ± 5 | 161 ± 2 | 0.05:0.00:0.95 |
P2 | 1117 ± 9 | 284 ± 2 | 0.90:0.00:0.10 |
P3 | 1169 ± 7 | 269 ± 2 | 0.53:0.00:0.47 |
P4 | 1195 ± 8 | 273 ± 2 | 0.47:0.00:0.53 |
P5 | 1201 ± 8 | 254 ± 2 | 0.24:0.00:0.76 |
P6 | 1199 ± 9 | 260 ± 3 | 0.26:0.00:0.74 |
The error on the relative sublevel populations is approximately 0.02.