Table 2. Complexes and H2O2 concentration for the kinetics experiments at 25°C and pH 7.
Experiment | [H2O2] = fixed | [complex] = fixed | ||
---|---|---|---|---|
[H2O2]0/ mol dm-3 | [complex]0/ mol dm-3 | [H2O2]0/ mol dm-3 | [complex]0/ mol dm-3 | |
[Co(L)(H 2 O)](ClO 4 ) 2 | 2.19 | 2.19×10−3–1.09×10−2 | 0.60–4.20 | 3.0×10−3 |
[Ni(HL)](ClO 4 ) 2 | 1.50 | 1.50×10−3–7.50×10−3 | 0.27–3.60 | 3.0×10−3 |
[Cu(HL)](ClO 4 ) 2 | 2.19 | 2.19×10−3–1.09×10−2 | 0.6 to 4.20 | 3.0×10−3 |