Table 5. Cyclic voltammetry data for the complexes.
[Co(L)(H2O)](ClO4)2 | [Ni(HL)](ClO4)2 | [Cu(HL)](ClO4)2 | |
---|---|---|---|
E pc (V) vs. Ag/AgCl | -0.641 | 0.812 | - 0.032 (I) |
-0.198 − -0.450 (II) | |||
E pa (V) vs. Ag/AgCl | 0.837 | 0.920 | 0.049 (I`) |
0.103 (II´) | |||
E 1/2 (V) vs. Ag/AgCl | - | 0.866 | 0.009 (I and I´) |
E 1/2 (V) vs. NHE | -0.432ª | 1.08 | 0.218 (I and I´) |
1.05 b | |||
ΔE(V) | - | 0.109 | 0.081 |
ΔE(V) internal standard | 0.347 | 0.347 | 0.347 |
a: E pc is given instead of E 1/2
b: E pa is given instead of E 1/2.