Table 2. Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions: Scope with Respect to the Allenoatea.


All data are the average of two experiments.
Yield of purified product, isolated as a mixture of diastereomers.
Determined through analysis by 1H NMR spectroscopy of the unpurified reaction mixture.
ee of the major diastereomer.
Catalyst loading: 10%.