Table 2. Polymers Prepared for Use in This Study.
| entry | [M]/[CTA] | conv.a | Mn(NMR)a [g mol–1] | Mn(SEC)b [g mol–1] | Đb | DPna |
|---|---|---|---|---|---|---|
| p(NIPAM)67 | 75 | 88.8 | 7500 | 9280 | 1.05 | 67 |
| p(NIPAM)152 | 600 | 25.3 | 17000 | 15500 | 1.27 | 152 |
| p(NIPAM)452 | 600 | 75.4 | 51000 | 55900 | 1.12 | 452 |
| p(OEGMA)224 | 650 | 34.4 | 67100 | 175749 | 1.92 | 224 |
| pHEA83 | 100 | 83.0 | 9900 | 10000c | 1.17 | 83 |
a
Determined from conversion of monomer to polymer by 1H NMR.
b
Determined by SEC in THF using PMMA polymer standards.
c
Determined by SEC in DMF (inc. 5 mM NH3BF4) relative to PMMA standards.