Table 1.
Crystal data and details of data collection for 1, 2 and 5.
| Comp. | 1 | 2 | 5 |
|---|---|---|---|
| formula | C34H72Cl3N3O5Ru | C88H180Cl12N9O20Ru4Y | C90H189Cl12DyN9O22.5Ru4 |
| Fw | 810.37 | 2603.00 | 2749.68 |
| space group |
P
|
P 21/c
|
Cc |
| α [Å] | 11.8503(7) | 18.4268(4) | 17.9596(12) |
| b [Å] | 18.0124(11) | 18.4268(4) | 27.2143(12) |
| c [Å] | 21.2370(14) | 18.4008(6) | 27.0644(16) |
| α [°] | 99.345(2) | ||
| β [°] | 104.935(3) | 92.962(4) | |
| γ [°] | 98.681(2) | ||
| V [Å3] | 4232.5(5) | 6247.9(3) | 13 210.3(13) |
| Z | 4 | 2 | 4 |
| λ [Å] | 0.71073 | 0.71073 | 0.71073 |
| ρcalcd [g cm−3] | 1.272 | 1.384 | 1.383 |
| size [mm3] | 0.30×0.30×0.20 | 0.18×0.18×0.16 | 0.30×0.20×0.16 |
| T [K] | 150(2) | 100(2) | 100(2) |
| μ [mm−1] | 0.598 | 1.247 | 1.307 |
| R1[a] | 0.0403 | 0.0278 | 0.0639 |
| wR2[b] | 0.1039 | 0.0746 | 0.1611 |
| GOF[c] | 1.033 | 1.052 | 1.129 |
[a] R1=Σ||Fo|−|Fc||/Σ|Fo|. [b] wR2={Σ[w(Fo2−Fc2)2]/Σ[w(Fo2)2]}1/2. [c] GOF={Σ[w(Fo2−Fc2)2]/(n−p)}1/2, where n is the number of reflections and p is the total number of parameters refined.