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(a) MSD versus time for the cations inside electrodes held at various potentials. The dashed line corresponds to a length scale characteristic of the average pore size. (b) Variation of the in-pore effective diffusion coefficients with the electrode potential. In the bulk electrolyte the diffusion coefficients of the ions are Dbulk ∼ 10–5 cm2 s–1 at 298 K. (c) Variation of the in-pore ionic concentrations (per gram of carbon electrode) with the electrode potential.
