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. 2015 Aug 13;54(40):11765–11769. doi: 10.1002/anie.201503152

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© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.

© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.

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Scheme 3 — Arylation of precursors 2 by SMC. [a] Reaction conditions in this case: [Pd(dba)₂] (4 mol %), XPhos (8 mol %), K₂CO₃ (3 equiv), toluene/H₂O, 80 °C, 20 h. dba=dibenzylideneacetone, XPhos=2-dicyclohexylphosphanyl-2′,4′,6′-triisopropylbiphenyl.