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Thermal ellipsoid (50%) rendering of the solid-state structure of 6. Hydrogen atoms omitted for clarity. Selected bond distances (Å) and angles (deg): Fe(1)–N(1) = 1.9459(13); Fe(1)–N(2) = 1.9730(13); Fe(1)–Br(1) = 2.3446(3); Fe(1)–Br(2) = 2.3188(3); Br(1)–Fe(1)–Br(2) = 116.068(11).
