Table 1.
Comparison of selected bond lengths and spectroscopic parameters for complexes 8 -12.
Fe-P (Å, avg) |
Fe-S (Å, avg) |
Fe-S-Fe (°) | ν(NN) (cm−1) | |
---|---|---|---|---|
8 | 2.226 | 2.184 | 137.098(15) | 2017, 1979 |
9 | 2.291 | 2.208 | 135.52(5) | 2070, 1983 |
10 | 2.341 | 2.244 | 138.02(4) | 2129 |
11 | 2.264 | 2.189 | 136.562(15) | 2036, 2093 |
12 | 2.219 | 2.332 | 140.42(3) | 2044, 1981 |