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. 2015 Oct 8;10:6395–6410. doi: 10.2147/IJN.S91961

Table 2.

Molecular weight characterization of mPEG-PCL and mPEG-PCL-Phe(Boc) by GPC

Copolymer MNa MWa PDIa MNb
mPEG-PCL 6,411 6,868 1.071 3,654
mPEG-PCL-Phe(Boc) 6,712 7,143 1.064 3,826

Notes: Relative molecular weights (MN, MW) and molecular weight distribution (PDI, MW/MN) were determined by a GPC system. The number-average molecular weights (MNs) from the GPC results were derived using a polystyrene calibration curve and were corrected by a factor of 0.57.

a

Obtained from GPC based on the polystyrene calibration.

b

Corrected GPC results, MNa ×0.57.

Abbreviations: mPEG-PCL, monomethoxyl poly (ethylene glycol)-b-poly (ε-caprolactone); mPEG-PCL-Phe(Boc), N-t-butoxycarbonyl-phenylalanine terminated monomethoxyl poly (ethylene glycol)-b-poly (ε-caprolactone); GPC, gel permeation chromatography; MN, number-average molecular weight; MW, weight-average molecular weight; PDI, polydispersity index.