Table 2.
Copolymer | MNa | MWa | PDIa | MNb |
---|---|---|---|---|
mPEG-PCL | 6,411 | 6,868 | 1.071 | 3,654 |
mPEG-PCL-Phe(Boc) | 6,712 | 7,143 | 1.064 | 3,826 |
Notes: Relative molecular weights (MN, MW) and molecular weight distribution (PDI, MW/MN) were determined by a GPC system. The number-average molecular weights (MNs) from the GPC results were derived using a polystyrene calibration curve and were corrected by a factor of 0.57.
Obtained from GPC based on the polystyrene calibration.
Corrected GPC results, MNa ×0.57.
Abbreviations: mPEG-PCL, monomethoxyl poly (ethylene glycol)-b-poly (ε-caprolactone); mPEG-PCL-Phe(Boc), N-t-butoxycarbonyl-phenylalanine terminated monomethoxyl poly (ethylene glycol)-b-poly (ε-caprolactone); GPC, gel permeation chromatography; MN, number-average molecular weight; MW, weight-average molecular weight; PDI, polydispersity index.