FIG. 5.

Simulated TD RR spectrum of the benzyl radical with an excitation wavelength of 320 nm (transition to the D₃ electronic level) with the AH (solid line, red) and the VH (solid line, green) models. The spectra calculated with the simplified AS (dashed line, red) and VG (dashed line, green) are also reported. For all spectra, Lorentzian broadening functions with HWHM of 30 cm⁻¹ have been used.