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. Author manuscript; available in PMC: 2015 Oct 21.
Published in final edited form as: J Am Chem Soc. 2015 May 19;137(22):7111–7121. doi: 10.1021/jacs.5b00498

Figure 4.

Figure 4

“Cone model” for ENDOR-derived constraints on the distances between C5′ of the anAdo• radical and the carbons and deuterons of Lys. The anAdo• 2pπ orbital is orienated towards the 2-C of Lys. Following the practice of McCracken and co-workers,45 the direction of a C5′-nucleus vector is shown as lying roughly within the cone associated with the nucleus, and similarly for the 3-C–D vector. All distances are shown in Table 1.